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CA 02961889 2017-03-20 WO 2016/028826 PCT/US2015/045777 R12and R12' taken together can be cyclized to form -(CH2)pX(CH2)s-; wherein each R12and R12' may independently optionally be substituted with 1 to 3 substituents selected from the group consisting of halogen, OR", alkoxy, heterocycloalkyl, -NR11C(0)NR11Rir, — C(0)NR11R11', _ NR11C(0)R11', -CN, oxo, -NR11502R11, -0C(0)R11, -502NR11RIT, _ SOR-13 , -S(0)2R13, — COOH and -C(0)0R13; each R'3 is independently alkyl, aryl, arylalkyl, heteroaryl, or heteroarylalkyl, each of which may optionally be substituted with -(CH2)OH; each R14is independently alkoxy, alkoxycarbonyl, -C(0)NR12R12', _NR" NR11C(0)NR11R11', or -N-heteroaryl; each R15is independently -(CH2)pN(R12)C(0)R12', -(CH2)pCN, — (CH2)pN(R12)C(0)0R12', — (CH2)pN(R12)C(0)NR12R12', _(CH2)pN(R12)502R12, -(CH2)pS02NR12R12', _(CH2)pC(0)NR12R12', _ (CH2)pC(0)0R12, -(CH2)p0C(0)0R12, -(CH2)p0C(0)R12, -(CH2)p0C(0)NR12R12', _ (CH2)pN(R12)502NR12R12', -(CF12)p0R12, -( CF12)p0C( 0)N ( R12)( CH2)m0 FI, — (CF12)pSOR12, — (CH2)pS02R12, -(CHApN Ri1R11 or -(CH2)pOCH2C(0)N(R12)(CH2),,OH; each R16is independently halo, alkyl, alkenyl, alkynyl, alkoxy, — (CH2)pNR11C(0)NR11R11', _ (CH2)pC(0)NR11R1v, -(CH2)pNR11C(0)R11', -CN, -(CH2)pNR11S02R11', — (CH2)p0C(0)R11, — (CH2)pS02NR11R11', _(CH2)pSOR13, -(CH2)pCOOH or -(CH2)p(C(0)0R13; X is CR11R11, 0, S, best cardarine gw 50156
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. CA 02961889 2017-03-20 WO 2016/028826 PCT/US2015/045777  In some embodiments, the ghrelin variant is macimorelin, which has the molecular formula, C26H301\1603, and the following structure: =NH 0 0 NNH H H 0 101  U, best cardarine reddit
. CA 02961889 2017-03-20 WO 2016/028826 PCT/US2015/045777  In some embodiments, the ghrelin variant is ipamorelin, which has the molecular formula, C38H49N905, and the following structure: tigriki. The following sequences were prepared and tested in the assay described in Example 5, best cardarine gw 501516
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